The cleanest stimulant ever made is water.
A 2000 study (Srámek et al.) measured blood chemistry before and after cold-water immersion. Dopamine rose 2.5× baseline and stayed elevated for hours. Norepinephrine rose 5.3×.
Translation: motivation, focus, and drive on tap. No caffeine. No crash. No tolerance build-up. The effect is largest the first time and stays meaningful with daily use.